Synthesis of SiO 2 @Ag Nanocomposite for Investigating Metal-Enhanced Fluorescence and Surface-Enhanced Raman Spectroscopy

SiO 2 @Ag nanocomposite (NC) has been synthesized by the chemical reduction and Stӧber method for Metal-enhanced fluorescence (MEF) of Rhodmine 6G (R6G) and Surface-enhanced Raman spectroscopy (SERS) of Malachite green (MG). As-synthesized SiO 2 @Ag NC indicated SiO 2 nanosphere (NS) and Ag nanoparticle (NP) morphologies. The SiO 2 @Ag NC was high quality with a well-defined crystallite phase with average sizes of 24 nm and 132 nm for Ag NP and SiO 2 NC, respectively. By using SiO 2 @Ag NC, the photoluminescence (PL) intensity of the R6G (at 59.17 ppm) was increased approximately 133 times. The SERS of the MG (at 1.0 ppm) with SiO 2 @Ag NC as substrate clearly observed vibrational modes in MG dye at 798, 916, 1172, 1394, and 1616 cm −1 . As a result, the SERS enhancement factor (EF SERS ) at 1172 cm −1 obtained 6.3 × 10 6 . This initial study points to the potential of SiO 2 @Ag NC as a promising material for MEF and SERS substrates to detect dyes at low concentrations.