Alternate Organic and Inorganic Molecular Layers

Jong Soo Do,Tai Hwan Ha, Jong Dal, Hong, Kwan Kim

semanticscholar(2020)

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摘要
1. (a) Schreider, H.-J. Angew. Chem. Int. Ed. Engl. 1993, 32, 848; (b) Webb, T. H.; Wilcox, C. S. Chem.Soc. Rew. 1993, 383 and references therein. 2. (a) Cram, D. J. Angew. Chem. Int. Ed. Engl. 1986, 25, 1093; (b) Lehn, J.-M. Angew. Chem. Int. Ed. Engl. 1988, 27, 89; (c )Perderson, C. J. Angew. Chem. Int. Ed. Engl. 1988, 27, 1021. 3. (a) Kilburn, J. D.; Mackenzie, A. R.; Still, W. C. J. Am. Chem. Soc. 1988, 110, 1307; (b) Sanderson, P. E. J.; Kil­ burn, J. D.; Still, W. C. J. Am. Chem. Soc. 1989, 111, 8314; (c) Liu, R.; Sanderson, P. E. J.; Still, W. C. J. Org. Chem. 1990, 55, 5184. 4. (a) Freidinger, R. M.; Veber, D. F.; Perlow, D. S.; Brooks, J. R.; Saperstein, R. Science, 1980, 210, 656; (b) Freidinger, R. M. J. Org. Chem. 1985, 50, 3631. 5. Mohamedi, F.; Richard, N. G.; Guida, W. C.; Liskamp, R.; Lipton, M.; Canfield, C.; Chang, G.; Hendrickson, T.; Still, W. C. J. Comp. Chem. 1990, 11, 440. 6. A conformer with the open cavity exists 1.5 kcal/mol abbve the global minimun conformer with the collapsed cavity. 7. To confirm this idea, a receptor 3 (R!=R2=Me) was pre­ pared from cu-methyl alanine. CPK modeling study on 3 suggest that the low energy conformer of 3 has the struc­ Bull. Korean Chem. Soc. 1998, Vol. 19, No. 2 257
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