Synthesis and crystal structure of racemic (R*,R*)-2,2′-(1,4-phenyl­ene)bis­(3-phenyl-2,3,5,6-tetra­hydro-4H-1,3-thia­zin-4-one)

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS(2021)

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摘要
In the racemic title compound, C26H24N2O2S2, one of the thia­zine rings shows a twisted boat conformation (Q = 0.743 Å, θ = 92.1°) and the other a half-chair puckering (Q = 0.669 Å, θ = 54.3°). The terminal phenyl rings are almost parallel to each other [dihedral angle 21.71 (10)°]. Both of these rings are orthogonal to the central phenyl ring, subtending a dihedral angle of about 78° in each case. The extended structure is consolidated by C—H⋯O and C—H⋯S hydrogen bonds as well as aromatic ring inter­actions of parallel-displaced and T-type. The mol­ecule has approximate C2 local symmetry but this is not carried over to its three-dimensional structure or the inter­molecular inter­actions.
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关键词
bis-heterocycle, twisted boat pucker, half-chair pucker and 1,3-thiazin-4-one, C-H center dot center dot center dot S hydrogen bonding, crystal structure
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