Solvothermal synthesis of 3D hierarchical Cu2FeSnS4 microspheres for photocatalytic degradation of organic pollutants.

In this work, we prepared Cu2FeSnS4 (CFTS) microspheres via solvothermal method and studied their photocatalytic performance towards the degradation of organic pollutants. With increasing solvothermal temperature from 160 °C to 180 °C, the morphology of CFTS changes from irregular 2D to hierarchical 3D shapes. Hierarchical 3D CFTS microspheres packed with 2D nanosheets were successfully prepared at 180 °C. During the solvothermal process, octadecyl amine (ODA) acts as a capping agent to prevent the aggregation of particles, while L-cystine functions as an environmentally friendly sulfur source and complexing reagent. The large surface area and mesoporous structure of the as-prepared 3D hierarchical CFTS microspheres provide more active sites, enhance visible light absorption and promote charge separation and transfer, leading to the improved photodegradation performance for RhB and MB compared to the samples prepared at the temperature lower than 180 °C. This work provides a simple and low-cost method for the synthesis of 3D hierarchical CFTS towards photocatalytic applications.