Dinitrogen-derived (diarylboryl)diazenido complexes with differing coordination to the thallium cation
DALTON TRANSACTIONS(2022)
Abstract
To prepare N-2-derived cationic boryldiazenido-tungsten complexes as models of semimetallic metal-borinium frustrated Lewis pairs activating N-2, we have attempted halide abstraction from trans-(diarylboryl)diazenido-halo-tungsten complexes. Reactions with Tl+ led to adducts in which coordination of the cation differs depending on the boryldiazenide substituents and the ancillary ligand. Chloride scavenging was not observed.
MoreTranslated text
Key words
thallium cation,complexes,dinitrogen-derived
AI Read Science
Must-Reading Tree
Example
![](https://originalfileserver.aminer.cn/sys/aminer/pubs/mrt_preview.jpeg)
Generate MRT to find the research sequence of this paper
Chat Paper
Summary is being generated by the instructions you defined