Metalla-phenalene complexes: synthesis, structure and aromaticity
CHEMICAL COMMUNICATIONS(2022)
Abstract
Metallaaromatics show a diversity of aromaticity. In this work, we report the synthesis and structural characterization of the first rhena-phenalene complexes. In addition to the Huckel aromaticity and sigma-aromaticity, pseudo pi anti-aromaticity is observed. DFT computations show that this anti-aromaticity (paramagnetic properties) is induced by the fused aromatic naphthyl ring.
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Key words
complexes,aromaticity,metalla-phenalene
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