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Ethane/ethylene separation in a metal-organic framework with shape-matching ethane traps

Nan Lu,Qiang Gao,Yan-Mei Zhang,Yuan Gao, Lin-Ying Wu,Yao-An Zhao,Li-Zhuang Chen

Journal of Solid State Chemistry（2021）

Cited 3|Views12
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Abstract
Ethylene (C2H4) plays an important role in industrial production and energy-efficiency separation C2H4 and C2H6 is one of the important processes for the sustainable development of petrochemical industry. Herein, we chose CPM-35 equipping ethane traps for adsorption separation of C2H6/C2H4. The experiment and computation results show that C2H6 can be priority adsorbed (IAST C2H6/C2H4 selectivity is 1.51 ​at 298 ​K and 1 ​bar) and the purification of C2H4 can be realized by this material.
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Key words
Metal-organic framework,C2H6/C2H4 separation,Reversed adsorption relationship,Shape-matching trap
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