Quinoxalinophenanthrophenazine Based Cruciforms

Lucas Ueberricke, Dennis Mizioch,Farhad Ghalami, Felix Mildner,Frank Rominger,Thomas Oeser,Marcus Elstner,Michael Mastalerz

European Journal of Organic Chemistry（2021）

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摘要

A series of cruciform aryl-substituted quinoxalinophenanthrophenazine derivatives (QPPs) was synthesized through Suzuki-Miyaura cross-coupling of a 2,7-diborylated pyrene tetraketal building block. The QPPs were analyzed for their optoelectronic properties by absorption and emission spectroscopy, cyclic voltammetry and quantum-chemical calculations. The solid-state packing was investigated as well and evaluated for its charge transport properties by calculated charge transfer integrals.

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关键词

Charge transport,Cross-coupling,Nitrogen heterocycles,π Stacking,Quinoxalinophenanthrophenazines (QPPs)

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