Carbon (Sp(3)) Tetrel Bonding Mediated Bodipy Supramolecular Assembly Via Unprecedented Synergy Of C-Sp3 Center Dot Center Dot Center Dot N And C-Sp3 Center Dot Center Dot Center Dot F Pair Interactions

Here, we present the first example of sp(3) hybridized carbon centered (C-sp3) tetrel bonding mediated 3D BODIPY assembly via the exceptional synergy of C-sp3 center dot center dot center dot N and C-sp3 center dot center dot center dot F pair interactions. The carbon tetrel bond interaction energies of C-sp3 center dot center dot center dot N and C-sp3 center dot center dot center dot F are amplified significantly as the size of the 1D chain grows from dimer to tetramer BODIPY units.