Synergistic Effects Of Photoinduced Electron Transfer And Heavy Atom Effect Based On Bodipy For Efficient Triplet Photosensitizers

Achieving a long triplet lifetime and a high triplet quantum yield for efficient triplet sensitizers are crucial for commercializing triplet-triplet annihilation-upconversion (TTA-UC). Although many donor-acceptor (D-A) or heavy atom-based triplet sensitizers have been extensively studied, each strategy suffers from major drawbacks, such as low triplet quantum yield of D-A and short triplet lifetime of heavy atoms. Herein, we propose the integration of a donor-acceptor with a heavy atom, which improves both triplet lifetime and quantum yield because of the simultaneous utilization of photoinduced electron transfer and the heavy atom effect. To prove this, we synthesized Triphenylamine(D)-BODIPY(A)-bromine(H) (AM6, AM7, and AM8), which were compared with standards such as Triphenylamine(D)-BODIPY(A) (AM2) and BODIPY-Bromine (AM9). The donor-acceptorheavy atom (D-A-H) compounds (AM6, AM7, AM8) exhibited excellent TTA-UC emission efficiency (3.9-6.5 %), which were high compared to AM2 (1.5 %) and AM9 (1.7 %). Moreover, threshold intensity (I-th) of AM6, AM7 and AM8 were lower (176-465 mW/cm(2)) than AM9 (1,916 mW/cm(2)), even though they had heavy atom. This demonstrates that D-A-H is an effective molecular design for triplet sensitizers with a synergistic effect.