Cationic ruthenium(II)-NHC pincer complexes with hemilabile COD: Solid-state structural characterization and theoretical study of an η2-(E,Z)-COD ligand

Dibya Yadav,Rahul Kumar Singh,Suryabhan Singh,Parasharam M. Shirage,Amrendra K. Singh

Journal of Organometallic Chemistry（2021）

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摘要

•Ruthenium (II)-NHC Pincer Complexes with Hemilabile COD and DMSO as ligands.•Solid-state characterization of a Ru complex with η2-COD ligand.•DFT studies on isomeric forms with η2-COD ligand.•Investigation of catalytic activity in transfer hydrogenation reactions.•No dissociation or hydrogenation of the COD ligand.

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关键词

Ru-complex,N-heterocyclic carbene,Hemilabile COD ligand,CNC pincer ligand,Transfer hydrogenation catalysis

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