Efficient protocol for the SO2F2-mediated deoxyfluorination of aliphatic alcohols

Cayo Lee,Joey Lai,Maxim Epifanov, Cindy Xinyun Wang,Glenn M. Sammis

Journal of Fluorine Chemistry（2021）

引用 7|浏览1

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摘要

•New, mild SO2F2-mediated deoxyfluorination reaction.•Efficient for both primary and secondary alcohols.•The alkyl fluorides can be accessed at room temperature in an hour.•Net inversion of configuration is observed with only minor deterioration of the ee.

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关键词

Sulfur(VI) fluorides,Sulfuryl fluoride,Alkyl fluoride,Deoxyfluorination,Ex situ gas generation

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