Strange behaviour of transport properties in novel metal thiocyanate based ionic liquids

Oscar Cabeza,Luisa Segade,Montserrat Domínguez-Pérez,Esther Rilo,David Ausín,Julio A. Seijas,M. Pilar Vazquez-Tato, Vladimir Matleev,Alexandr Ievlev,Josefa Salgado,Luis M. Varela

Journal of Molecular Liquids（2021）

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摘要

•We present transport properties for nine novel ionic liquids BMIMn-zM+z(SCN)n.•Metal cations are: Al, Mn, Fe, Cr, Ni, Hg, Zn, Co and Cu; and BMIM(SCN).•Ionic conductivity, viscosity and diffusion constant vs. temperature are given.•Comparison of the three magnitudes in pairs with classical equations agrees.•In contrast, great differences in the data presented for the different compounds.

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关键词

Thiocyanate ionic liquids,Ionic conductivity,Viscosity,Diffusion coefficient

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