Tailoring The Griffiths-Like Cluster Formation In The Insulator Ferromagnet Spin-Glass Gd2nixco1-Xmno6 Double Perovskite
PHYSICAL REVIEW B(2021)
Abstract
In this paper we present the effects of the composition on structural, vibrational, magnetic, and electronic properties of double perovskite 3d based manganese oxides Gd2NixCo1-xMnO6 (GNCMO) powder (for 0 < x < 1) prepared by high temperature solid state chemistry. These compounds have a great research interest due to their specific physical properties. We have shown that the synthesized compounds exhibit ferromagnetic interaction between the spins of (Mn4+, Co2+), and (Mn4+, Ni2+) cations via oxygen ions and antiferromagnetic interactions between (Gd3+, Co2+), (Gd3+, Ni2+) and (Gd3+, Gd3+) and present a paramagnetic to ferromagnetic phase transition. The paramagnetic Curie-Weiss temperature of GNCMO (T-c) increases from 121to 128K as the nickel content increases from 0.2 to 0.8. Further, temperature dependent inverse magnetic susceptibility chi(T)(-1) shows deviation from Curie Weiss behavior around T-G which depicts that Griffiths phase already observed in several perovskite compounds. The value of the GP percentage and the exponent of (lambda < 1) are found to increase as the nickel content increases. The hysteresis curve at T = 20K for x = 0.2 displays a metamagnetic transition explained by the reorientation of the Gd spin moments towards theMn, Co, and Ni spin moments. The imaginary part of susceptibility chi '' shows a small shift of the peak similar to 1 K indicating the presence of spin or cluster glass behavior.
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Key words
insulator,cluster,griffiths-like,spin-glass
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