The yielding of attractive gels of nanocrystal cellulose (CNC)

The flow behavior of nanocrystalline cellulose (CNC) hydrogels in the presence of a monovalent electrolyte (NaCl) as a function of CNC and salt concentration is explored using a variety of linear and nonlinear rheological tests. We have first observed an apparent "slip yield stress" at small wall shear stress values that is mainly due to the onset of solidlike slippage of the hydrogels before their true yielding and deformation. This flow regime and the "slip yield stress" can be eliminated using a sandpaper of an optimum grit size. At higher wall shear stress values, two yielding points for the CNC/salt network are seen in strain sweep tests due to network disruption and cluster deformation that depend on the concentration of both CNC (1-5 wt. %) and electrolyte (0-100 mM). The first yield stress is due to yielding and flow of clusters, while the second one is due to breakage of clusters to small flocs and individual fibers. These yielding stresses were obtained by a variety of tests including strain amplitude sweep, creep, and steady shear, and their values are compared confirming their existence. Rheo-SALS (small angle light scattering) measurements confirmed structural changes as the scattering patterns change from isotropic to highly anisotropic with an increase of deformation and rate of deformation. Moreover, confocal laser scanning microscopy and polarized microscopy images confirm the gradual breakup of clusters to smaller ones and eventually to nearly individual fibers with an increase in the applied shear strain and rate.