Palladium‐Catalyzed Carbonylation in the Synthesis of N‐Ynonylsulfoximines

Ding Ma,Chenyang Wang,Deshen Kong,Yongliang Tu,Peng Shi,Carsten Bolm

Advanced Synthesis and Catalysis（2021）

Cited 13|Views4

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Abstract

Palladium‐catalyzed carbonylation reactions with Cr(CO)6 as carbonyl source are key for the preparation of N‐ynonylsulfoximines from NH‐sulfoximines and bromoalkynes. The couplings proceed at room temperature with a wide range of substrate combinations affording the corresponding products in good yields.

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Key words

carbonylation,chromium hexacarbonyl,palladium catalysis,sulfoximines,ynones

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