Exploration of the Influence Mechanism of La Doping on the Arc Erosion Resistance of Ag/SnO 2 Contact Materials by a Laser-Simulated Arc

JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE(2021)

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Abstract
To explore the influence mechanism of La doping on the arc erosion resistance of Ag/SnO 2 contact materials, SnO 2 and La-doped SnO 2 are prepared by a chemical coprecipitation method, and then Ag/SnO 2 and La-doped Ag/SnO 2 contact materials are prepared by a powder metallurgy process. The microstructures and phase structures of the Ag/SnO 2 and La-doped Ag/SnO 2 contact materials before and after arc erosion are analyzed. A laser-simulated arc is used as the experimental arc to explore the micromorphology and physicochemical properties of SnO 2 and La-doped SnO 2 after laser-simulated arc erosion. The results show that the density, hardness and conductivity of the La-doped Ag/SnO 2 contact material all increase first and then decrease with an increasing La content, reaching their highest values at a La/Sn molar ratio of approximately 0.25. La doping improves the dispersion of SnO 2 in the Ag matrix and reduces the mass loss of the La-doped Ag/SnO 2 contact material during the arc erosion process. Under the action of a laser-simulated arc, although both parts of the SnO 2 and La-doped SnO 2 transform into SnO, most of the SnO 2 sample forms large aggregates, while the La-doped SnO 2 sample forms small, spherical particles that are well dispersed. Finally, a mechanism is proposed whereby La doping enhances the arc erosion resistance of Ag/SnO 2 contact materials.
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Key words
Ag/SnO2 contact material,arc erosion,La-doped SnO2,laser-simulated arc
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