Phase Changing Poly(Ionic Liquid) With Electrolytic Functionality For A Single-Layer Ionogel-Based Smart Window With Multi-Stimuli Response
SOLAR ENERGY MATERIALS AND SOLAR CELLS(2021)
摘要
Functional materials play a crucial role in the design of smart windows that can provide a more comfortable indoor environment for people to enjoy a better lifestyle. A traditional smart window material tends to have only a single feature wherein the color change is led by solar energy input. It was known that different color tones have a significant influence on people's emotions. Herein, our group has adopted a strategy to combine the properties of an electroand thermo-chromic in a single layer (all-in-one) ionogel. In this work, 3-chloro-N-isopropylacetamide containing thermo-responsive poly [VNIm][TFSI] based electroactive has been synthesized for multi-responsive device. Ionogel, consisting of MBV [TFSI], ferrocene, and poly [VNIm][TFSI], was utilized to construct a single layer (all-in-one) device (with and without water). The proposed ionogel based device 1 (with water) that could offer a useful response to surrounding environments by switching between opaque and transparent in the aqueous condition through a temperature change. This kind of device 1 can be utilized as an individual privacy smart windows, under specific conditions. On the other hand, the ionogel based device 2 (without water) exhibits remarkable electrochromic performance through a reversible color change between colorless to purple color once 1.8 V was applied at 25 degrees C (below UCST) and gave a high (Delta T) of 74.9% and a coloration efficiency (CE) of 229.03 cm(2) C-1 with coloration and bleaching times of 10.2 s and 100 s, respectively, while the tone changes from purple to blue when the device 2 is above UCST (52 degrees C). These phenomena are caused by the synergetic effect of its electrochromic reaction and thermochromic behavior. The device 2 maintained its switching stability for >2000 cycles. This novel strategy of integrating thermo-and electrochromic materials into a single device will lead to the development of the next generation of multifunctional smart windows.
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关键词
Thermo-responsive, Ionogel-based device, All-in-one device, Thermo- and electro-chromic, Smart window
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