Improved synthesis of halo- and oxonium derivatives of dodecahydrido-closo -dodecaborate(2-)
JOURNAL OF ORGANOMETALLIC CHEMISTRY(2021)
Abstract
Convenient methods have been developed to synthesize cyclic oxonium derivatives with tetrahydrofurane, tetrahydropyrane, and 1,4-dioxane, as well as pure mono-halo derivatives (halo = chloro, bromo, iodo) of dodecahydrido-closo-dodecaborate(2-). (c) 2021 Elsevier B.V. All rights reserved.
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Key words
Dodecaborate(2-),Dodecahydrido-closo-dodecaborate(2-),Cyclic oxonium dodecaborate,Monohalogenated dodecaborate,N-halosuccinimide
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