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Improved synthesis of halo- and oxonium derivatives of dodecahydrido-closo -dodecaborate(2-)

Mahmoud Al-Joumhawy, Paula Cendoya, Akim Shmalko, Tarek Marei, Detlef Gabel

JOURNAL OF ORGANOMETALLIC CHEMISTRY（2021）

Cited 6|Views0
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Abstract
Convenient methods have been developed to synthesize cyclic oxonium derivatives with tetrahydrofurane, tetrahydropyrane, and 1,4-dioxane, as well as pure mono-halo derivatives (halo = chloro, bromo, iodo) of dodecahydrido-closo-dodecaborate(2-). (c) 2021 Elsevier B.V. All rights reserved.
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Key words
Dodecaborate(2-),Dodecahydrido-closo-dodecaborate(2-),Cyclic oxonium dodecaborate,Monohalogenated dodecaborate,N-halosuccinimide
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