Self-template biomass-derived nitrogen and oxygen co-doped porous carbon for symmetrical supercapacitor and dye adsorption

Advanced Composites and Hybrid Materials(2021)

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摘要
Exploring high-efficiency, green, low-cost, and sustainable biomass waste materials to solve energy shortage and environmental contamination issues is still a significant challenge. Herein, self-template corncob porous carbon (CPC) with bifunctions, high oxygen (16.34 at%), and nitrogen content (2.30 at%) was obtained by a simple carbonization-activation method. Benefiting from the high specific surface area, porous structure and high oxygen and nitrogen content of the prepared CPC, the optimal CPC-700-2 exhibited a higher special capacitance of 295.93 F g –1 at the current density of 1 A g –1 , good rate capability (170 F g –1 at 50 A g –1 ), and excellent stability and circularity. Significantly, the CPC-based symmetric supercapacitor demonstrated a high energy density (9.9 Wh kg −1 ) at a power density of 250 W kg −1 , and exceptional cyclic stability. More interestingly, the CPC also has an efficient sewage purification capacity. The adsorption test confirmed that the CPC possesses a higher adsorption capacity and removal rate for Rh B (249.06 mg g –1 and 99.87%). This satisfactory performance provides a potential way for the high value-added utilization of agricultural and forestry waste. Graphical abstract
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关键词
Corncob,Porous carbon,Supercapacitor,Electrode,Adsorption
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