Proton-coupled redox properties and water oxidation catalysis of an aqua-coordinated (µ-oxo)diruthenium(III) complex

Bo-Hong Luo,Ya-Jie Ren,Hai-Bin Cui,Qiang Fu, Hao-Dong Jiang, Huan-Fa Du,Qin Xie, Peng Li,Hua-Xin Zhang,Tian-Shun Wang

Inorganica Chimica Acta（2021）

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摘要

An oxo-bridged diruthenium(III) complex showing proton-coupled electron transfer behaviors in aqueous media at pH 0–14 was active for catalytic water oxidation in acidic conditions, which was studied using electrochemical and chemical oxidation.

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关键词

Ruthenium complex,Proton-coupled electron transfer,Catalysis,Water oxidation reaction

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