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Rh(III)‐Catalyzed Csp2−Csp3 Bond Cleavage/Carbonylethylation of α‐Indolyl Alcohols

Zhipeng Liu,Xinwei Hu,Can Yang,Haisheng Xie,Huanfeng Jiang,Wei Zeng

Advanced Synthesis and Catalysis（2021）

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Abstract
A Rh(III)‐catalyzed Csp2−Csp3 bond cleavage/carbonylethylation of α‐indolyl alcohols with allylic alcohols has been reported. This transformation involved a cascade C−C bond cleavage/C−C bond formation, and provides a novel approach to assemble 2‐carbonylethylindole skeletons.
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Key words
Rh(III)-Catalysis,Carbonylethylation,α-Indolyl alcohols,Allylic alcohols,C−C bond cleavage
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