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Mediating covalent crosslinking of single-chain nanoparticles through solvophobicity in organic solvents

Georg M. Scheutz, Justine Elgoyhen,Kyle C. Bentz,Yening Xia,Hao Sun,Junpeng Zhao,Daniel A. Savin,Brent S. Sumerlin

Polymer Chemistry（2021）

Cited 7|Views6
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Abstract
We describe the photoinduced intrachain crosslinking of coumarin-containing copolymers in various organic solvents. Analysis of copolymer solvation and comparison to a molecular coumarin derivative revealed solvophobicity-driven crosslinking kinetics and chain compaction that facilitated the synthesis of single-chain nanoparticles.
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