Preparation And Dielectric Properties Of Co-Contained Unfilled Tungsten Bronze Ceramics Ba4rco0.5nb9.5o30

In this study, Ba4RCo0.5Nb9.5O30 (R = La, Nd, Sm, Eu) (BRCN) ceramics were synthesized using a high-temperature solid-state reaction. The XRD refinement results show that ceramic samples are tetragonal tungsten bronze (TTB). As the radius of rare-earth ions decreases, the unit cell volume of BRCN ceramics decreases, and the radius difference between Ba2+ and R ions increase, which results in BO6 octahedral distortion and the Raman peaks shift to high frequency. In addition, as the radius of rare-earth ions decreases, the ionic displacements increase and thus the dielectric constant peak temperature goes up. The high-temperature impedance results show that there exists n-type electronic conduction in the samples. The remanent polarization of the P-E curve at low frequencies increases from 0.470 to 1.038 mu C cm(-2) as the rare-earth ion radius decreases.