An Unprecedented Bridging Phcnoxyl Radical In Dicopper(Ii) Complexes: Evidence For An S=3/2 Spin State

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION(2005)

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摘要
Cooperativity between metal centers and a bridging radical ligand, reflected by ferromagnetic exchange coupling, was studied with the dicopper complex shown. The stability, and thus the reactivity of the complex, is finely tuned by both the nuclearity of the complex and the nature of the coordinating solvent X. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2005/z461462_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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关键词
bridging ligands, copper, EPR spectroscopy, magnetic properties, radicals
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