Ba3b10o17f2 Center Dot 0.1kf: The First Mixed Alkali/Alkaline-Earth Metal Fluorooxoborate With Unprecedented Double-Layered B-O/F Anionic Arrangement

Yahui Li, Hongwei Yu,Guopeng Han,Hao Li,Zhihua Yang,Shilie Pan

CHEMICAL COMMUNICATIONS（2019）

Cited 13|Views2

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Abstract

The diverse oxyfluoride species and vast number of different topological arrangements lead to fluorooxoborates' structural beauty and richness. Herein, the first mixed alkali/alkaline-earth metal fluoro-oxoborate Ba3B10O17F2 center dot 0.1KF was successfully synthesized and systemically characterized. Its most important structural feature is an unprecedented double-layered B-O/F anionic arrangement.

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