Low-Temperature Luminescence Spectrum Of Forbidden 4f(13)5d-4f(14) Transitions In Caf2:Lu3+ Crystal
MAGNETIC RESONANCE IN SOLIDS(2019)
Abstract
The Lu3+ 4f(13)5d-4f(14) VUV luminescence in CaF2:Lu3+ crystal at 8K was studied with a high spectral resolution using synchrotron radiation excitation. Absence of a zero-phonon line in the recorded spectrum was explained and features in the recorded spectrum were reproduced by simulation based on the microscopic model of electron-phonon interaction and the developed theory of non-Condon spectra.
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Key words
5d-4f luminescence, electron-phonon interaction, non-Condon effect, lanthanides, CaF2:Lu3+
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