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Catalytic Aerobic Oxidative Decarboxylation Of Alpha-Hydroxy-Acids. Methyl Mandelate As A Benzoyl Anion Equivalent

G Blay, B Fernandez,P Formentin,Jr Pedro, Al Rosello, R Ruiz,Y Journaux

TETRAHEDRON LETTERS（1998）

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Abstract
The monomeric square-planar cobalt(III) complex of bis-N,N'-disubstituted oxamides catalyses the oxidative decarboxylation of alpha-hydroxy acids with molecular oxygen/pivalaldehyde with very good yields. This reaction offers an interesting alternative in the use of methyl mandelate as a convenient benzoyl anion equivalent. (C) 1998 Elsevier Science Ltd. All rights reserved.
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Key words
oxidation, decarboxylation, cobalt, catalysis
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