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Total Synthesis Of Applanatumols X And Y

Kyohei Uchida,Yuichiro Kawamoto,Toyoharu Kobayashi,Hisanaka Ito

TETRAHEDRON LETTERS（2020）

Cited 3|Views2
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Abstract
The first total synthesis of applanatumols X and Y, isolated from Ganoderma applanatum, have been accomplished in 9 and 10 steps, respectively, using the key intermediate in the synthesis of applanatumol B. The synthesis features an efficient construction of the tricyclic skeleton with high stereochemical control. (C) 2020 Elsevier Ltd. All rights reserved.
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Key words
Meroterpenoid, Applanatumol, Stereoselective cyclization, Total synthesis
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