Nanometer-Size Semiconductor And Oxide Clusters Prepared Via Colloidal Processes

A Kasuya,G Milczarek,I Dmitruk, Y Barnakov,R Czajka, O Perales, X Liu, S Tsunekawa, H Takahashi, K Tohji,B Jeyadevan,K Shinoda, T Ogawa, T Arai

PROCEEDINGS OF THE INTERNATIONAL SYMPOSIUM ON CLUSTER ASSEMBLED MATERIALS（2001）

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摘要

Semiconductor and oxide clusters were prepared in solution by chemical reactions, photo-etching and liquid chromatography. Electrodeposition technique is also applied to produce cluster-assembled films. Physical and chemical properties of these clusters were analyzed with respect to specific materials functions in nanometer scale. Clusters of II-VI semiconductor stabilize at several discrete sizes and shapes in the diameter range of 1 to 3 nm. Electro-deposited clusters of II-VI semiconductor assembled in a thin film show high activities in photoelectrolysis of H2S.

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关键词

nano-clusters, nano-technology, photo-electrolysis, photo-etching, electro-deposition, solution technique

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