A New Kind Of Void Soap-Free P(Mma-Ea-Maa) Latex Particles

CHINESE CHEMICAL LETTERS(2005)

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摘要
Soap-free P(MMA-EA-MAA) particles with narrow size distribution were synthesized by seeded emulsion polymerization of methyl methacrylate (MMA), ethyl acrylate (EA) and methacrylic acid (MAA), and large voids inside the particles were generated by alkali posttreatment in the presence of 2-butanone. Results indicated that the size of void and the particle volume were related with the amount of 2-butanone. The generation mechanism of voids was proposed.
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关键词
particle morphology, soap-free latex particles, seeded emulsion polymerization, alkali posttreatment
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