Some Aspects Of The Aqueous Solution Chemistry Of The Na+/Ca2+/Oh-/Cit(3-) System: The Structure Of A New Calcium Citrate Complex Forming Under Hyperalkaline Conditions

In the present study, we show that in hyperalkaline (pH > 13) aqueous solutions, Ca2+ forms a new, so far unknown complex species with the citrate ion, the structure of which is different from the well-known CaCit((aq))(-) species present in solutions of close to neutral pH. The solubility of Ca(3)Cit(2(s)) was found to increase significantly under hyperalkaline conditions. The decrease in the electric conductivity and the variations observed in the freezing point depression of such solutions also indicate complexation. From H-1 NMR measurements, in this complex, the citrate ion is suggested to be in quadruply deprotonated form. From the variation of the (2)J(HH) geminal proton coupling constant, two neighboring carboxylate groups are coordinated to the calcium ion in a monodentate mode (besides the alcoholate). The optimal structure of the complex with the composition of CaCitH(-1(aq))(2-) has also been calculated using DFT calculations, applying the Polarizable Continuum Model. Sodium ion-pairing was found to compete efficiently with this calcium complexation process, and in solutions with high Na-ion content, the equilibria are shifted towards the formation of NaCit((aq))(2-) and Na(2)Cit((aq))(-) ion pairs. (C) 2016 Elsevier B.V. All rights reserved.