Heterometallic Al6Zn12 nano-plate with pi-conjugated ligand: synthesis and nonlinear absorption properties
CHEMICAL COMMUNICATIONS(2021)
Abstract
Presented herein is the synthesis, structure, and optical properties of the aluminum(III)-zinc(II) heterometallic compound AlOC-57. This compound was found to form a large unit cell (approximately sixteen thousand atoms) and a three-shell nano-plate structure. Based on the Z-scan patterns, the third-order nonlinear optical response of the heterometallic nano-plate was mainly attributed to its nonlinear absorption (reverse saturable absorption).
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