Synergistic Copper/Enamine Catalysis for the Regio-, Stereo-, and Enantioselective Intermolecular alpha-Addition of Aldehydes to Allenamides
ORGANIC LETTERS(2021)
摘要
We herein describe an intermolecular enantioselective alpha-addition of aldehydes to allenamides using a dual copper/enamine catalytic system. Highly enantioselective addition of aldehydes was obtained thanks to secondary amine catalysts. The process was found to be highly regio-, stereo-, and enantioselective under mild conditions.
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关键词
copper/enamine catalysis,aldehydes
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