Scalable Synthesis Of [8]Cycloparaphenyleneacetylene Carbon Nanohoop Using Alkyne Metathesis
CHEMICAL COMMUNICATIONS(2021)
摘要
Large scale synthesis of cycloparaphenyleneacetylenes has been challenging due to low macrocyclization yields and harsh aromatization methods that often decompose strained alkynes. Herein, a cis-stilbene-based building block is subjected to alkyne metathesis macrocylization. The following sequence of alkene-selective bromination and dehydrobromination afforded a [8]cycloparaphenyleneacetylene derivative in high yield with good scalability. X-Ray crystal structure and computational analysis revealed a unique same-rim conformation for the eight methyl groups on the nanohoop.
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关键词
alkyne metathesis,carbon,scalable synthesis
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