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Electrochemical hydrogen formation catalysed by a Pd-8 string

Tomoaki Tanase,Kanako Nakamae,Haruka Miyano, Yoshimi Fujisawa,Yasuyuki Ura,Takayuki Nakajima

CHEMICAL COMMUNICATIONS（2021）

Cited 4|Views9
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Abstract
The linear Pd-8 complex supported by tetraphosphines reacted with HBF4 to give an unprecedented linear tetrapalladium complex with a terminal hydride, which promoted electrocatalytic hydrogen formation from HBF4 in acetonitrile. The 1D coordination polymer of Pd-8 chain confined within Nafion film was applied to the electrocatalytic H-2 formation.
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electrochemical hydrogen formation,pd<sub>8</sub>
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