Easy Access To Secondary And Tertiary Alcohols Via Metal-Free And Light Mediated Radical Carbonyl Allylation
CHEMICAL COMMUNICATIONS(2021)
Abstract
Here we report a strategy for carbonyl addition with unactivated alkenes using an organic photocatalyst on both aldehyde and ketone substrates. This protocol grants us a good alternative to the traditional Barbier-Grignard allylation that exhibits poor functional group tolerance. With this method the stoichiometric use of metals can be avoided, high atom economy can be achieved and fewer by-products are generated.
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Key words
Transition Metal Catalysis
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