Oxidative C-H/C-H Coupling Of Dipyrromethanes With Azines By Tio2-Based Photocatalytic System. Synthesis Of New Bodipy Dyes And Their Photophysical And Electrochemical Properties
MOLECULES(2021)
摘要
Oxidative C-H/C-H coupling reactions of dipyrromethanes with azines in the presence of a heterophase oxidative photocatalytic system (O-2/TiO2/visible light irradiation) were carried out. As a result of cyclization of obtained compounds with boron trifluoride etherate, new hetaryl-containing derivatives of 4,4-difluoro-4-boron-3a,4a-diaza-s-indacene were synthesized. For the obtained compounds, absorption and luminescence spectra, quantum yields of luminescence as well as cyclic volt-amperograms were measured.
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关键词
dipyrromethane, BODIPY, azine, TiO2, C-H, C-H couplings, ONSH, photocatalysis
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