Seasonal variation, source identification, and risk assessment of organophosphate ester flame retardants and plasticizers in surficial sediments from Liao River estuary wetland, China

Organophosphate ester (OPE) flame retardants and plasticizers in surficial sediments were collected in Liao River estuarine wetland during the dry, flood, and level periods to understand the seasonal variation, potential sources, and environmental risks. The concentrations of ∑13OPEs ranged from 19.5 to 67.0 ng g−1 dry weight (dw), with an average concentration of 30.6 ng g−1 dw. OPEs pollution displayed a seasonal variation, the concentrations of OPEs in dry period > level period > flood period. Tributyl-n-phosphate was the predominant OPEs, which accounts for 29.7% of ∑13OPEs. Principal component analysis and positive matrix factorization suggested that the pollution sources of OPEs also varied seasonally. The ecological risk of OPEs to aquatic organisms was low, and the non-carcinogenic and carcinogenic risks to human beings were also far below the acceptable level. 2-Ethylhexyl diphenyl phosphate was the major compound causing ecological and non-carcinogenic risk, while tris-(2-chloroethyl) phosphate had the highest carcinogenic risk.