Preparation of carboxymethyl starch/polyvinyl-alcohol electrospun composite nanofibers from a green approach.

A green approach for the preparation of starch-based composite nanofibers using electrospinning was developed. The water-soluble sodium carboxymethyl starch (CMS) with DS 0.31 was prepared. The addition of co-blending polymer polyvinyl-alcohol (PVA) was attempted to improve the CMS solution spinnability, which blends from aqueous solution were prepared at different CMS/PVA weight ratios. The solution parameters including viscosity, surface tension and conductivity were measured and the morphologies of nanofibers were observed by SEM. Smooth, continuous, and defect-free nanofibers were successfully obtained range from the blend of CMS/PVA weight ratios of 10:90 to 80:20. Diameter distribution diagrams suggested that the diameter of the nanofibers reduced with the concentration of CMS increasing. This is the first report that the thin nanofiber (135.29 nm) with bead-free was obtained at the maximal CMS content of 50.0 wt% in the CMS/PVA blend. This study provided a green approach to produce starch-based nano-scale fibers.