Alkaline-Driven Liquid Metal Janus Micromotor With A Coating Material-Dependent Propulsion Mechanism

Micro/nanomotors have achieved huge progress in driving power divergence and accurate maneuver manipulations in the last two decades. However, there are still several obstacles to the potential biomedical applications, with respect to their biotoxicity and biocompatibility. Gallium- and indium-based liquid metal (LM) alloys are outstanding candidates for solving these issues due to their good biocompatibility and low biotoxicity. Hereby, we fabricate LM Janus micromotors (LMJMs) through ultrasonically dispersing GaInSn LM into microparticles and sputtering different materials as demanded to tune their moving performance. These LMJMs can move in alkaline solution due to the reaction between Ga and NaOH. There are two driving mechanisms when sputtering materials are metallic or nonmetallic. One is self-electrophoresis when sputtering materials are metallic, and the other one is self-diffusiophoresis when sputtering materials are nonmetallic. Our LMJMs can flip between those two modes by varying the deposited materials. The self-electrophoresis-driven LMJMs' moving speed is much faster than the self-diffusiophoresis-driven LMJMs' speed. The reason is that the former occurs galvanic corrosion reaction, while the latter is correlated to chemical corrosion reaction. The switching of the driving mechanism of the LMJMs can be used to fit into different biochemical application scenarios.