Octahedral Hexachloro Environment Of Dy3+ With Slow Magnetic Relaxation And Luminescent Properties

Nesrine Benamara,Mayoro Diop,Cédric Leuvrey,Marc Lenertz,Pierre Gilliot,Mathieu Gallart,Hélène Bolvin,Fatima Setifi,Guillaume Rogez,Pierre Rabu,Emilie Delahaye

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY（2021）

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摘要

The compound [BiCNIm](3)[DyCl6] was synthesized from a nitrile-functionalized imidazolium ionic liquid [BiCNIm][Cl] and DyCl3 . 6H(2)O in acetonitrile using solvothermal conditions. Structural characterization reveals that the Dy3+ ions are in a quasi-regular octahedral environment, formed by six chloride anions. The magnetic study indicates that this mononuclear compound exhibits a Single Ion Magnet behaviour. This behaviour is compared to that of other mononuclear compounds containing Dy3+ ions in various octahedral environment.

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关键词

Ionic liquid, Imidazolium salt, Lanthanide, Single ion magnet, Luminescence

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