Tuning the excitation wavelength of luminescent Mn2+-doped ZnSxSe1-x obtained by mechanically induced self-sustaining reaction

Mn2+-doped ZnSxSe1–x solid solution samples (Mn:ZnSxSe1-x) were synthesized by the mechanochemical process denoted as mechanically-induced self-sustaining reaction from Mn/Zn/S/Se powder elemental mixtures. The samples were characterized by X-ray diffraction, scanning electron microscopy, diffuse reflectance UV–Vis spectroscopy and emission and excitation photoluminescence measurements. The band-gap energy of samples was controlled by changing the stoichiometry, x, of the solid solution. All samples showed the characteristic Mn2+ 4T1-6A1 emission at ~588 nm when exciting the host material, so it was possible to tune the excitation wavelength from 349 nm to 467 nm. However, an efficiency loss was observed with increasing Se content, probably due to the overlap between the absorption and emission spectra that induced self-absorption and emission quenching.