Thermally induced transformation of a Cu4I4-based cluster to a Cu2I2-based cluster under mild conditions
DALTON TRANSACTIONS(2021)
摘要
A reaction of 6,6 '-bis((benzylthio)methyl)-2,2 '-bipyridine (L) with CuI at room temperature led to one Cu4I4-based cluster, which could be thermally transformed to a Cu2I2-based one under mild conditions due to the formation of a Cu-S bond. Along with the structural transformation, remarkable changes in the color and luminescence have been triggered.
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