The gains from breaking symmetry
NATURE CHEMISTRY(2021)
摘要
ll-carbon quaternary centres are challenging targets in organic synthesis. Now, the development of a zinc-catalysed desymmetrization method enables the synthesis of chiral alcohols with all-carbon quaternary centres by the selective reduction of symmetrical α,α-disubstituted malonates.
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关键词
Asymmetric catalysis,Asymmetric synthesis,Synthetic chemistry methodology,Chemistry/Food Science,general,Analytical Chemistry,Organic Chemistry,Physical Chemistry,Inorganic Chemistry,Biochemistry
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