A Europium-Organic Framework Sensing Material For 2-Aminoacetophenone, A Bacterial Biomarker In Water

INORGANIC CHEMISTRY(2021)

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摘要
2-Aminoacetophenone (2-AA) is a metabolite produced in large quantities by the pathogenic bacteria Pseudomonas aeruginosa (PA), which is a biomarker for PA in water. State-of-the-art analytical techniques to detect PA usually require expensive instruments and a long analysis time which are not suitable for real-time water quality monitoring, especially for high-quality drinking water. Herein, we reported the application of a europium metal-organic framework (Eu-MOF) as a luminescent sensing material, which provides a facile, environmentally friendly and low-cost way for the fast detection of PA in water. Eu-MOF shows a high sensitivity toward 2-AA with a K-SV value of 3.563 x 10(4) M-1, rapid luminescence response in 12 s and high-selectivity and anti-interference ability with the existence of common detection indexes in drinking water owing to the good match of the energy levels of Eu-MOF and 2-AA. A systematical optimization of the sensing conditions to enhance the sensing function of Eu-MOF for 2-AA was discussed in detail, to give fundamentals for the rational design of MOF-based sensing materials.
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europium–organic framework sensing material,bacterial biomarker,europium–organic framework
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