Tuning the magnetic and electric behavior of lithium ferrite using an eco-friendly pectin sol-gel route

JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY(2021)

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摘要
Lithium ferrite (LiFe 5 O 8 ) in the cubic crystal system is a very important and versatile material for several technological applications as it possesses very attractive electric and magnetic behaviors. Herein, we report an ecofriendly first approach sol-gel route, mediated by pectin, for the preparation of LiFe 5 O 8 . Pectin, a natural polysaccharide, was explored because it is a very attractive gelling agent to produce ceramic materials by the sol-gel method. The influence of the sintering temperature (800–1200 °C) applied on the pressed pellets, was evaluated by correlating the electric and magnetic properties with its structural and morphological characteristics. LiFe 5 O 8 pellets sintered at 1000 and 1100 °C had the lowest dielectric losses and the most interesting dielectric behaviors in this regard, due to quasi-independence of the loss tangent through the temperature and frequency range studied. The magnetization, at 300 K, of LiFe 5 O 8 monophasic pellets, sintered at 1100 and 1200 °C, are among the best values reported in the literature, 65 and 71 emu/g, respectively. Thus, the LiFe 5 O 8 prepared by this sol-gel route shows particularly notable magnetic properties that can be explored for several applications. Tuning the magnetic and electric behavior of lithium ferrite using an eco-friendly pectin sol-gel route
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关键词
Sol-gel route, Lithium ferrite, Dielectric properties, Magnetic properties
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