Calorimetric and spectroscopic studies of interactions of PPI G4 dendrimer with tegafur in aqueous solutions
Journal of Molecular Liquids(2021)
Abstract
•PPI G4 dendrimer binds about 30 molecules of tegafur (TF).•Complexation of PPI G4 with TF is exothermic and occurs spontaneously.•TF molecules are bound with surface part of PPI G4 macromolecules.•Hydrophobic tetrahydrofuran part of TF stabilizes supramolecular complex.
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Key words
PPI G4 dendrimer,Amino-terminated macromolecule,Tegafur,Isothermal titration calorimetry,Equilibrium dialysis, solubility measurements
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