Generation Of Aryllithium Reagents From N-Arylpyrroles Using Lithium

Tomoya Ozaki,Atsushi Kaga,Hayate Saito,Hideki Yorimitsu

SYNTHESIS-STUTTGART（2021）

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摘要

Treatment of 1-aryl-2,5-diphenylpyrroles with lithium powder in tetrahydrofuran at 0 degrees C results in the generation of the corresponding aryllithium reagents through reductive C-N bond cleavage.

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关键词

organolithium reagents, C-N bond cleavage, lithium, pyrroles, metalation, reduction, deamination

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