Synthesis And Optical And Electronic Properties Of One-Dimensional Sulfoxonium-Based Hybrid Metal Halide (Ch3)(3)Sopbi3

Yuki Tanaka,Shiqiang Bai,Xizu Wang,Si Yin Tee,Siew Lay Lim,Lin Ke, Surani B Dolmanan,Coryl Jing Jun Lee,Poh Chong Lim,Xiang Yao,Jishan Wu,Ming-Yong Han

CHEMICAL COMMUNICATIONS（2021）

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Abstract

We report the synthesis and optical and electronic properties of a one-dimensional sulfoxonium-based hybrid metal halide in an orthorhombic crystal system with a Pnma space group. To provide direct insights, a method is developed to calculate tolerance factors with the ionic radii of non-spherical cations from X-ray crystallographic data.

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Key words

hybrid metal halide,electronic properties,one-dimensional,sulfoxonium-based

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